[1]程贤达,孙建伟,贾煦,等.豫西成矿带潭头盆地金矿区农田土壤重金属污染及来源解析[J].华东地质,2022,43(03):313-323.[doi:10.16788/j.hddz.32-1865/P.2022.03.007]
　CHENG Xianda,SUN Jianwei,JIA Xu,et al.Pollution and source apportionment of heavy metals in the farmland soils of the gold mining area in Tantou Basin, western Henan metallogenic belt[J].East China Geology,2022,43(03):313-323.[doi:10.16788/j.hddz.32-1865/P.2022.03.007]
点击复制

豫西成矿带潭头盆地金矿区农田土壤重金属污染及来源解析()
分享到：

《华东地质》[ISSN:2096-1871/CN:32-1865/P]

卷:
43
期数:
2022年03期
页码:
313-323
栏目:
生态地质
出版日期:
2022-09-24

文章信息/Info

Title:
Pollution and source apportionment of heavy metals in the farmland soils of the gold mining area in Tantou Basin, western Henan metallogenic belt
作者:
程贤达1;  孙建伟1;  贾煦1; 2;  商连南1;  张龙1; 3;  孙亚柯1
1. 中国地质调查局西安矿产资源调查中心, 陕西 西安 710100;
2. 中国地质大学(北京)地球物理与信息技术学院, 北京 100083;
3. 长安大学地球科学与资源学院, 陕西 西安 710054
Author(s):
CHENG Xianda1;  SUN Jianwei1;  JIA Xu1; 2;  SHANG Liannan1;  ZHANG Long1; 3;  SUN Yake1
1. Xi’an Center of Mineral Resources Survey, China Geological Survey, Xi’an, 710100, Shaanxi, China;
2. School of Geophysics and Information Technology, China University of Geosciences, Beijing, 100083, China;
3. School of Earth Sciences and Resources, Chang’an University, Xi’an, 710054, Shaanxi, China
关键词:
金矿区; 土壤; 重金属污染; 潭头盆地; 豫西成矿带
Keywords:
gold mining area; soil; heavy metal pollution; Tantou Basin; Western Henan metallogenic belt
分类号:
X53
DOI:
10.16788/j.hddz.32-1865/P.2022.03.007
摘要:
为查明豫西成矿带潭头盆地金矿区农田土壤重金属污染特征及污染来源,在该盆地农田中系统采集土壤样品,分析土壤中的重金属含量,采用聚类分析和主成分分析/绝对主成分分数(PCA/APCS)受体模型对污染源进行解析并计算污染源贡献率。结果显示:研究区农田土壤重金属Hg、As、Cr、Ni、Cu、Pb、Zn、Cd含量平均值均低于农用地土壤污染风险筛选值,整体土壤污染风险较低,仅部分样品Hg、As、Cu、Pb、Zn、Cd含量超过风险筛选值;Pb、Zn和Cd主要呈区域性污染,其他重金属元素主要呈孤立点状污染。Hg、Cd、Pb变异系数达到强变异水平,表明潭头盆地农田土壤中Hg、Cd、Pb元素受人类活动干扰比较强烈。综合聚类分析、主成分分析及空间分布特征,8种重金属主要来源于4类污染源:Cu、Pb、Zn和Cd污染来源于交通源(PC1);Cr和Ni污染来源于自然源(PC2);As污染来源于与金矿开采和尾矿堆存相关的矿业源(PC3);Hg污染来源于与小作坊汞溶解炼金相关的矿业源(PC4)。
Abstract:
Heavy metals contents of soil samples from the gold mining areas in Tantou Basin of the western Henan metallogenic belt were analyzed to determine the pollution characteristics and sources. The authors used the Cluster analysis and Principal Component Analysis/Absolute Principal Component Scores (PCA/APCS) receptor model to identify the pollution source and its contribution rate. The results showed that the average contents of Hg, As, Cr, Ni, Cu, Pb, Zn, and Cd of the farmland soil in the study area are lower than risk control standard for soil contamination of agricultural land, indicating lower risk of soil pollution in the gold mining area of the Tantou Basin. However, some samples showed excess contents of Hg, As, Cu, Pb, Zn and Cd elements with regional pollution in Pb, Zn, and Cd and point pollution in other heavy metal elements. The variable coefficients of Hg, Cd, and Pb are at a strong variation level, indicating that they were strongly influenced by anthropogenic activities. Combining the results of cluster analysis, principal component analysis and the spatial distribution characteristics, the eight heavy metals mainly come from four types of pollution sources: Cu, Pb, Zn, and Cd pollutions origin from traffic source (PC1); Cr and Ni pollutions come from the natural source (PC2); both As and Hg pollutions are derived from mining source but the former is related to gold mining and tailings stockpiling (PC3) and the latter is related to small workshop mercury dissolution smelting (PC4).

参考文献/References:

[1] 周永章,宋书巧,杨志军,等.河流沿岸土壤对上游矿山及矿业开发的环境地球化学响应:以广西刁江流域为例[J].地质通报, 2005, 24(10/11):945-951. ZHOU Y Z, SONG S Q, YANG Z J, et al. Environment geochemical response of soils along banks of a river to mines and mining activities in the upper reaches of the river-A case study of the Diaojiang River drainage system, Guangxi, China[J]. Geological Bulletin of China, 2005, 24(10/11):945-951.
[2] 王庆仁,刘秀梅,崔岩山,等.我国几个工矿与污灌区土壤重金属污染状况及原因探讨[J].环境科学学报, 2002, 22(3):354-358. WANG Q R, LIU X M, CUI Y S, et al.Soil contamination and sources of heavy metals at individual sites of industry and mining associate with wastewater irrigation in China[J]. Acta Scientiae Circumstantiae, 2002, 22(3):354-358.
[3] 徐友宁,张江华,柯海玲,等.矿业活动区农田土壤重金属累积风险的评判方法:以小秦岭金矿区为例[J].地质通报, 2014, 33(8):1097-1105. XU Y N, ZHANG J H, KE H L, et al. An assessment method for heavy metal cumulative risk on farmland soil in the mining area:A case study of the Xiaoqingling gold mining area[J]. Geological Bulletin of China, 2014, 33(8):1097-1105.
[4] 赖斯颖,曹容浩,谭桂丽.福建省龙海市南部表层土壤重金属元素累积特征研究[J].华东地质, 2021, 42(1):29-36. LAI S Y, CAO R H, TAN G L, et al. Study on accumulation characteristics of heavy metal elements in topsoil of southern Longhai City, Fujian Province[J]. East China Geology, 2021, 42(1):29-36.
[5] BOCCA B, ALIMONTI A, PETRUCCI F, et al. Quantification of trace elements by Sector Field Inductively Coupled Plasma Mass Spectrometry in Urine, Serum, Blood and Cerebrospinal Fluid of Patients with Parkinson’s Disease[J]. Spectrochimica Acta Part B:Atomic Spcetroscopy, 2004, 59(4):559-566.
[6] 张开军,魏迎春,徐友宁.小秦岭某金矿区土壤-农作物重金属元素富集规律[J].地质通报, 2015, 34(11):2018-2023. ZHANG K J, WEI Y C, XU Y N. The discussion on heavy metal accumulation regularity in the soil and crop of the Xiaoqinling gold mining area[J]. Geological Bulletin of China, 2015, 34(11):2018-2023.
[7] WU Y G, XU Y N, ZHANG J H, et al. Evaluation of ecological risk and primary empirical research on heavy metals in polluted soil over Xiaoqingling gold mining region,Shaanxi,China[J]. Transactions of Nonferrous Metal Society of China, 2010, 20(4):688-694.
[8] 郄海满,文帮勇,王继强,等.江西赣州梓山地区富硒土壤重金属元素安全性评价[J].华东地质, 2017, 38(3):234-240. QIE H M, WEN B Y, WANG J Q, et al. Safety evalution of heavy metal contents in selenium-rich soils in Zishan area, Ganzhou, Jiangxi province[J]. East China Geology, 2017, 38(3):234-240.
[9] 宋泽峰,栾文楼,崔邢涛,等.冀东平原土壤重金属元素的来源分析[J].中国地质, 2010, 37(5):1530-1537. SONG Z F, LUAN W L, CUI X T,et al. An analysis of the sources of heavy metals in soils of eastern Hebei plain[J].Geology in China, 2010, 37(5):1530-1537.
[10] LIAO G L, LIAO D X, LI Q M. Heavy metals contamination characteristics in soil of different mining activity zones[J]. Transactions of Nonferrous Metals Society of China, 2008, 18:207-211.
[11] HE B, YUN Z J, SHI J B, et al. Research Progress of Heavy Metal Pollution in China:Sources, Analytical Methods, Status and Toxicity[J]. Chinese Science Bulletin, 2013, 58(2):134-140.
[12] SONG Y, XIE S, ZHANG Y, et al. Source apportionment of PM2.5 in Beijing using principal component analysis/absolute principal component scores and UNMIX[J]. Science of the Total Environment, 2006, 372:278-286.
[13] 瞿明凯,李卫东,张传荣,等.基于受体模型和地统计学相结合的土壤镉污染源解析[J].中国环境科学, 2013, 33(5):854-860. QU M K, LI W D, ZHANG C R, et al. Source apportionment of soil heavy metal Cd based on the combination of receptor model and geostatistics[J]. China Environmental Science, 2013, 33(5):854-860.
[14] 陈丹青,谢志宜,张雅静,等.基于PCA/APCS和地统计学的广州市土壤重金属来源解析[J].生态环境学报, 2016, 25(6):1014-1022. CHEN D Q, XIE Z Y, ZHANG Y J, et al. Source Apportionment of Soil Heavy Metals in Guangzhou Based on the PCA/APCS Model and Geostatistics[J]. Ecology and Environmental Sciences, 2016, 25(6):1014-1022.
[15] 袁宏,钟红梅,赵利,等.基于PCA/APCS受体模型的崇州市典型农田土壤重金属污染源解析[J].四川环境, 2019, 38(6):35-43. YUAN H, ZHONG H M, ZHAO L, et al. Analysis of Heavy Metal Pollution Sources of Typical Farmland Soils in Chongzhou City Based on PCA/APCS Receptor Model[J]. Sichuan Environment, 2019, 38(6):35-43.
[16] 王锐,邓海,严明书,等.重庆市酉阳县南部农田土壤重金属污染评估及来源解析[J].环境科学, 2020, 41(10):4749-4756. WANG R, DENG H, YAN M S, et al. Assessment and Source Analysis of Heavy Metal Pollution in Farmland Soils in Southern Youyang County,Chongqing[J]. Environmental Science, 2020, 41(10):4749-4756.
[17] 李淑娟.豫西潭头、汝阳盆地中新生代红层沉积环境研究[D].北京:中国地质大学(北京), 2010. LI S J. The study of depositional environment of Mesozoic and Cenozoic red beds in Tantou-Ruyang Basin, western Henan, China[D]. Beijng:University of Geosciences (Beijing), 2010.
[18] 江小均,柳永清,姬书安,等.豫西栾川-潭头盆地含脊椎动物化石地层序列和K/T界线初步研究[J].中国科学:地球科学, 2014, 41(5):738-744. JIANG X J, LIU Y Q, JI S A,et al. Dinosaur-bearing strata and K/T boundary in the Luanchuan-Tantou Basin of western Henan Province,China[J]. Scientia Sinica (Terrae), 2014, 41(5):738-744.
[19] 朱淑慧.豫西潭头盆地上白垩统-古新统沉积特征及物源分析[D].河南:河南理工大学, 2015. ZHU S H. Analysis on Sedimentary Characteristics and Provenances of Upper Cretaceous-Paleocene of Tantou Basin in West Henan[D]. Henan:Henan Polytechnic University, 2015.
[20] 中华人民共和国国土资源部. DZ/T0295-2016土地质量地球化学评价规范[S].北京:地质出版社, 2016:1-51. Ministry of Land and Resources of the People’s Republic of China. DZ/T0295-2016 Specification of land quality geochemical assessment[S]. Beijing:Geological Publishing House, 2016:1-51.
[21] THURSTON G D, SPENGIER J D. A qualitative assessment of source contribution to inhalable particulate matter pollution in metropolitan Boston[J]. Atmospheric Environment, 1985, 18:1347-1355.
[22] 中华人民共和国生态环境部. GB15618-2018土壤环境质量农用地土壤污染风险管控标准(试行)[S].北京:中国环境出版社, 2018:1-4. Ministry of Ecology and Environment of the People’s Republic of China. GB 15618-2018 Soil environment quality-Risk control standard for soil contamination of agricultural land[S]. Beijing:China Environmental Science Press, 2018:1-4.
[23] 邵丰收,周皓韵.河南省主要元素的土壤环境背景值[J].河南农业, 1998, 10:28. SHAO F S, ZHOU H Y. Soil environmental background values of main elements in Henan Province[J]. Henan Agriculture, 1998, 10:28.
[24] 王运,邹勇军,王鹤,等.江西信丰油山地区土壤硒及重金属元素地球化学特征[J].华东地质, 2019, 40(2):152-160. WANG Y, ZOU Y J, WANG H, et al. Geochemical characteristics of Se and heavy metal elements in the soil of Youshan, Xinfeng County, Jiangxi Province[J]. East China Geology, 2019, 40(2):152-160.
[25] 刘青枰,邓时强,赵元艺,等.西藏尕尔勤矿床区域性土壤重金属元素地球化学特征及来源解析[J].地球学报, 2018, 39(4):481-490. LIU Q P, DENG S Q, ZHAO Y Y, et al. Sources Analysis and Element Geochemical Characteristics of Regional Soil Heavy Metals from the Ga’erqin Ore Deposit, Tibet[J]. Acta Geoscientica Sinica, 2018, 39(4):481-490.
[26] FACCHINELLI A, SACCHI E, MALLEN L. Multivariate statistical and GIS-based approach to identify heavy metal sources in soils[J]. Environmental Pollution, 2001, 114(3):313-324.
[27] 时立文.统计分析[M].北京:清华大学出版社, 2012:150-256. SHI L W. Statistical Analysis[M]. Beijing:Tsinghua University publishing house, 2012:150-256.
[28] 谭赛章,杨涛,可愚,等.海洋表层沉积物中金属镉的来源解析[J].海洋通报, 2019, 38(6):683-689. TAN S Z, YANG T, KE Y, et al. Source apportionment of metal Cd in the surfacemarine sediments[J]. Marine Science Bulletin, 2019, 38(6):683-689.
[29] 张亚飞,马嫣,亓鲁,等.南京北郊冬季PM2.5中芳香酸的测定及来源解析[J].环境科学, 2016, 37(7):2436-2442. ZHANG Y F, MA Y, QI L, et al. Determination and Source Apportionment of Aromatic Acids in PM2.5 from the Northern Suburb of Nanjing in Winter[J]. Environmental Science, 2016, 37(7):2436-2442.
[30] GUO H, WANG T, LOUIE P K K. Source apportionment of ambient non-methane hydrocarbons in Hong Kong:application of a principal component analysis/absolute principal component scores (PCA/APCS) receptor model[J]. Environmental Pollution, 2004, 129(3):489-498.
[31] SHELLY L M, MELISSA J A, EILEEN P D, et al. Source apportionment of exposures to volatile organic compounds. I. Evaluation of Receptor Models using simulated exposure data[J]. Atmospheric Environment, 2002, 36(32):3629-2641.
[32] 王学松,秦勇.徐州城市表层土壤中重金属元素的富积特征与来源识别[J].中国矿业大学学报, 2006, 35(1):84-88. WANG X S, QIN Y. Accumulation and identification of heavy metals in Xuzhou urban topsoil[J]. Journal of China University of Mining&Technology, 2006, 35(1):84-88.
[33] 仝致琦,谷蕾,段海静,等.基于Kriging插值的路旁土壤重金属含量空间分布——以310国道郑州-开封段为例[J].环境科学学报, 2012, 32(12):3030-3038. TONG Z Q, GU L, DUAN H J, et al. Spatial distribution of heavy metals in roadside soils based on Kriging interpolation:A case study of Zhengzhou-Kaifeng section along the 310th national highway[J]. Acta Scientiae Circumstantiae, 2012, 32(12):3030-3038.
[34] LESTAND, GRCMANH, ZUPANM, et al. Relationship of soil properties to fractionation of Pb and Zn in soil and their uptake into Plantago lanceolate[J]. Soil&Sediment Contamination, 2003, 12(4):507-522.
[35] ALLOWAY B J. Heavy metals in soils[M]. Dordrecht:Springer, 2013.
[36] 曹见飞,段欣荣,吴泉源,等.金矿区周边农田土壤重金属源解析研究——以焦家金矿为例[J].环境污染与防治, 2021, 43(5):546-552. CAO J F, DUAN X R, WU Q Y, et al. Source apportionment of soil heavy metals in surrounding farmland of gold mining:a case study of Jiaojia gold mine[J]. Environmental Pollution&Control, 2021, 43(5):546-552.
[37] 刘恢,刘志楼,杨姝,等.矿区生态环境修复丛书-有色冶金汞污染控制[M].北京:科学出版社, 2021:1-241. LIU H, LIU Z L, YANG S, et al. Control of mercury pollution in non-ferrous metallurgy[M]. Beijing:Science Press, 2021:1-241.
[38] WANG S X, ZHANG L, ZHAO B, et al. Mitigation potential of mercury emissions from coal-fired power plants in China[J]. Energy Fuels, 2012, 26(8):4635-4642.

相似文献/References:

[1]杨琼,杨忠芳,刘旭,等.广西典型酸性火成岩地质低背景区土壤-水稻重金属积累特征及生态风险[J].华东地质,2022,43(01):49.[doi:10.16788/j.hddz.32-1865/P.2022.01.005]
　YANG Qiong,YANG Zhongfang,LIU Xu,et al.Transfer characteristics and ecological risk assessment of heavy metals in soil-rice system in typical acid magmatic rock area with low geochemical background of Guangxi[J].East China Geology,2022,43(03):49.[doi:10.16788/j.hddz.32-1865/P.2022.01.005]
[2]邢润华,吴正,杜国强.安徽省宣州区土壤重金属污染风险评估及来源分析[J].华东地质,2022,43(03):336.[doi:10.16788/j.hddz.32-1865/P.2022.03.009]
　XING Runhua,WU Zheng,DU Guoqiang.Risk assessment and source analysis of soil heavy metal pollution in Xuanzhou District, Anhui Province[J].East China Geology,2022,43(03):336.[doi:10.16788/j.hddz.32-1865/P.2022.03.009]
[3]唐志敏,张晓东,张明,等.新安江流域土壤元素地球化学特征:来自岩石建造类型的约束[J].华东地质,2023,44(02):172.[doi:10.16788/j.hddz.32-1865/P.2023.02.006]
　TANG Zhimin,ZHANG Xiaodong,ZHANG Ming,et al.Geochemical characteristics of soil elements in Xin’an River Basin: constraints from rock formation types[J].East China Geology,2023,44(03):172.[doi:10.16788/j.hddz.32-1865/P.2023.02.006]

备注/Memo

备注/Memo:
收稿日期:2021-12-10;改回日期:2022-5-16。
基金项目:中国地质调查局"熊耳山-伏牛山矿集区生态修复支撑调查(编号:DD20208079)"项目资助。
作者简介:程贤达,1992年生,男,助理工程师,硕士,主要从事矿山地质环境调查与研究工作。Email:xiandacugb@163.com。
更新日期/Last Update: 1900-01-01