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    福建省宁化县土壤硒分布特征及影响因素

    Distribution of soil selenium in Ninghua County of Fujian Province and its influencing factors

    • 摘要: 为了探讨福建省宁化县土壤硒分布和富集特征,文章通过多目标区域地球化学调查,系统采集了表层土壤组合样品621件和深层土壤组合样品158件,研究土壤硒的地球化学特征和影响因素等。结果表明:①表层土壤硒含量为0.09~1.05 mg/kg,平均值为0.21 mg/kg,深层土壤硒含量为0.09~0.61 mg/kg,平均值为0.24 mg/kg,晚寒武纪东坑口组(∈4d)和震旦纪西溪组(Zx)发育的土壤中硒含量最高,平均值分别为0.47 mg/kg和0.40 mg/kg;②表层土壤总体上属于富硒、硒适量土壤,富硒土壤面积为283.20 km2,占11.76%,且在不同类型的土壤中,硒平均含量呈现出黄壤>红壤>水稻土>紫色土的特点;③部分区域表层土壤的硒相对于深层土壤表现出明显的富集特征,强烈富集区域与富硒土壤区域基本吻合,具有开发富硒农产品的潜力;④相关分析表明,土壤硒含量与TOC、TFe2O3、Mn等呈显著正相关,与pH呈显著负相关,说明土壤理化性质、铁锰氧化物等对硒的表生地球化学行为有重要影响。

       

      Abstract: To investigate the distribution and enrichment of selenium in the soils of Ninghua County, Fujian Province, we have conducted a multi-purpose regional geochemical survey by systematically collecting a total of 621 surface soil composite samples and 158 deep soil composite samples, which were used to study the geochemical characteristics and influencing factors of soil selenium. The results showed that the selenium content in surface soil range from 0.09 to 1.05 mg/kg with an average of 0.21 mg/kg, while in deep soil it range from 0.09 to 0.61 mg/kg with an average of 0.24 mg/kg. The highest selenium content was found in the soils derived from the Dongkengkou Formation(∈4d) of the Late Cambrian and the Xixi Formation(Zx) of the Sinian, with averages of 0.47 mg/kg and 0.40 mg/kg respectively. The surface soils are generally selenium-rich and selenium-sufficient, with a selenium-rich soil area of 283.20km2, accounting for 11.76%. The average selenium content in different soil types are characterized as yellow soil>red soil>paddy soil>purple soil. In some areas, the selenium content in surface soil showed a more significant enrichment than that in deep soil, and the intensely enriched areas basically coincided with the selenium-rich soil areas, indicating the potential for developing selenium-rich agricultural products. Correlation analysis show that the selenium content in soil has significantly positive correlation with organic carbon, total iron oxide and manganese, and apparently negative correlation with pH, indicating that the physicochemical properties of soil and iron-manganese oxides have an important impact on the surficial geochemical behavior of selenium.

       

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