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    苏北阜宁县地下水水化学特征及成因分析

    Hydrochemical characteristics and genesis of the groundwater in Funing County, Northern Jiangsu

    • 摘要: 为了查明苏北阜宁县潜水和承压水的水化学成因和补给特征,文章采集区域内地表水、潜水、承压水(第Ⅱ、第Ⅲ、第Ⅳ承压水)的水样,结合数理统计分析、Piper三线图、Gibbs模型和水化学特征系数等手段,分析了不同水体的氢氧同位素关系和矿化度分布、主要阴阳离子关系、水化学特征。结果表明:① 阜宁县地下水总体为弱碱性,潜水和承压水中阳离子质量浓度都呈现Na+>Ca2+>Mg2+>K+,潜水中阴离子质量浓度呈现HCO-3>Cl->SO2-4>NO-3,第Ⅱ、第Ⅲ、第Ⅳ承压水中阴离子质量浓度皆呈现出HCO-3>SO2-4>Cl->NO-3;潜水的总溶解固体(TDS)比第Ⅱ、第Ⅲ、第Ⅳ承压水偏高,局部区域的潜水为微咸水和咸水,第Ⅱ、第Ⅲ、第Ⅳ承压水的水质明显优于潜水。② 地下水的补给与大气降水相关,潜水为现代降水补给,第Ⅱ、第Ⅲ、第Ⅳ承压水源于晚更新世或者更早时期的降水补给。③ 地下水水化学特性受降水影响较小,主要受到水岩作用、阳离子交换作用控制,其中第Ⅱ、第Ⅲ、第Ⅳ承压水的盐分主要来源于硅酸盐岩风化,人类活动对地下水化学组分影响相对较弱。

       

      Abstract: For investigating hydrochemical evolution and recharge characterisitcs of the groundwater in Funing County, northern Jiangsu Province, the study collected various water samples from regional surface water, phreatic water and confined water (the Ⅱ, Ⅲ and Ⅳ confined water) and analyzed their hydrogen and oxygen isotopes (δ18O-δD) relations, distributive rules of water salinity, major ions’ relations and hydrochemical characteristics in combination of mathematical statistical analysis, Piper three-line diagram, Gibbs model and hydrochemical characteristic coefficient. The results show that: ① the groundwater in Funing is weakly alkaline in general, mass concentration of cations in both phreatic water and confined water are distributed in the sequence of Na+>Ca2+>Mg2+>K+; those of anions in the phreatic water presents as HCO-3>Cl->SO2-4>NO-3while that in the Ⅱ, Ⅲ and Ⅳ confined water presents as HCO-3>SO2-4>Cl->NO-3; The total dissolved solids (TDS) of the phreatic water is relatively higher than that of the Ⅱ, Ⅲ and Ⅳ confined water, with locally brackish and saline water; The water quality in the confined area is significantly better than that in the phreatic area. ② The groundwater recharge in the study area is related to the atmospheric precipitation. The phreatic water is closely associated with modern precipitation while the Ⅱ, Ⅲ and Ⅳ confined water mainly sourced from precipitation replenishment in Late Pleistocene or even earlier; ③ The chemical characteristics of groundwater in the region are less affected by precipitation and more controlled by water rock interaction and cation exchange, among which the salinity of the Ⅱ, Ⅲ, and Ⅳ confined water mainly come from the weathering of silicate rocks, and human activities have slight impact on the chemical composition of the groundwater.

       

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