[1]李明辉,张笑蓉,杜国强,等.安徽石台仙寓地区土壤硒地球化学特征及生物效应[J].华东地质,2023,44(02):186-196.[doi:10.16788/j.hddz.32-1865/P.2023.02.007]
 LI Minghui,ZHANG Xiaorong,DU Guoqiang,et al.Geochemical characteristics and biological effect of soil selenium in the Xianyu area, Shitai County of Anhui Province[J].East China Geology,2023,44(02):186-196.[doi:10.16788/j.hddz.32-1865/P.2023.02.007]
点击复制

安徽石台仙寓地区土壤硒地球化学特征及生物效应()
分享到:

《华东地质》[ISSN:2096-1871/CN:32-1865/P]

卷:
44
期数:
2023年02期
页码:
186-196
栏目:
土壤资源专题
出版日期:
2023-06-17

文章信息/Info

Title:
Geochemical characteristics and biological effect of soil selenium in the Xianyu area, Shitai County of Anhui Province
作者:
李明辉 张笑蓉 杜国强 陶春军 吴正
安徽省地质调查院(安徽省地质科学研究所), 安徽 合肥 230001
Author(s):
LI Minghui ZHANG Xiaorong DU Guoqiang TAO Chunjun WU Zheng
Geological Survey of Anhui Province(Anhui Institute of Geological Sciences), Hefei 230001, Anhui, China
关键词:
地球化学特征生物效应仙寓地区安徽石台
Keywords:
seleniumgeochemical characteristicsbiological effectXianyu areaShitai County of Anhui Province
分类号:
P595X142
DOI:
10.16788/j.hddz.32-1865/P.2023.02.007
摘要:
为探讨安徽石台仙寓地区土壤-作物系统中硒的富集及迁移特征,在该区系统采集了岩石、土壤、灌溉水、农作物及根系土样品,研究土壤硒的地球化学特征、赋存状态、主要影响因素及生物有效性等。结果显示:研究区表层土壤硒含量为0.27~15.79 mg/kg,平均值为0.87 mg/kg,显著高于安徽省土壤背景值;土壤硒含量与有机质呈显著正相关,但与pH值无相关性;不同基岩地层的硒含量差异显著,其中蓝田组、荷塘组及皮园村组碳质页岩是该区土壤硒的主要物质来源;土壤硒形态主要为腐殖酸结合态、强有机结合态和残渣态,生物可直接利用形态的硒约占3%。研究区稻谷、茶叶对硒的平均富集系数分别为0.21和0.08,采集的水稻样品全部达到富硒标准,具有良好的富硒产业开发优势。
Abstract:
In order to understand the enrichment and migration behavior of selenium in the soil-crop system in the Xianyu area, Shitai County, Anhui Province, we systematically collected samples of rocks, soils (including root soils), irrigation water and crops to study selenium in terms of its geochemical features, occurrence status, main influencing factors and bioavailability. The results showed that the content of selenium in the topsoil of the study area ranged from 0.27 mg/kg to 15.79 mg/kg (0.87 mg/kg in average), and was evidently higher than the soil background value of Anhui Province. The content of selenium was positively correlated with organic matter, but unrelated to pH value of the soil. Various bedrock strata exhibit obviously different selenium content, which mainly sourced from carbonaceous shales of the Lantian Formation, Hetang Formation and Piyuancun Formation in the study area. Selenium is substantially humic acid-bound, strongly organically-bound and in its residual form in soil, of which only about 3% can be directly used by organisms. The average enrichment coefficient of selenium in paddy and tea of the study area is 0.21 and 0.08, respectively. All the paddy samples reached the selenium-rich standard, which implies that the local paddy has advantages in the development of selenium-rich products.

参考文献/References:

[1] 周国华.富硒土地资源研究进展与评价方法[J].岩矿测试,2020,39(3):319-336. ZHOU G H. Research progress of selenium-enriched land resources and evaluation methods[J]. Rock and Mineral Analysis,2020,39(3):319-336.
[2] 宋晓珂,李宗仁,王金贵.青海东部农田土壤硒分布特征及其影响因素[J].土壤,2018,50(4):755-761. SONG X K,LI Z R, WANG J G. Distribution and influential factors of soil Se in eastern Qinghai Province[J]. Soils, 2018,50(4):755-761.
[3] 谭见安.中华人民共和国地方病与环境图集[M].北京:科学出版社, 1989. TAN J A. The atlas endemic diseases and their environments in the People’s Republic of China[M]. Beijing: Science Press, 1989.
[4] 廖金凤.土壤环境中的硒对人和动物健康的影响[J].广东微量元素科学,2002(3):20-23. LIAO J F. Effect of selenium in soil on health of human beings and animals[J]. Guangdong Trace Elements Science, 2002(3):20-23.
[5] 雍太健,张明,陈国光,等.赣州市土地质量地球化学评估及其富硒特征研究[J].华东地质,2020,41(4):403-409. YONG T J,ZHANG M,CHEN G G, et al. Geochemical evaluation and selenium-rich characteristics of land quality in Ganzhou City[J].East China Geology,2020,41(4):403-409.
[6] 杨忠芳,余涛,侯青叶,等.海南岛农田土壤Se的地球化学特征[J].现代地质,2012,26(5):837-849. YANG Z F, YU T, HOU Q Y, et al. Geochemical characteristics of soil selenium in farmland of Hainan island[J].Geoscience,2012,26(5):837-849.
[7] 成晓梦,孙彬彬,贺灵,等.四川省沐川县西部地区土壤硒含量特征及影响因素[J].岩矿测试,2021,40(6):808-819. CHENG X M, SUN B B, HE L, et al. Content characteristics and influencing factors of soil selenium in western Muchuan County, Sichuan Province[J]. Rock and Mineral Analysis,2021,40(6): 808-819.
[8] 刘道荣,徐虹,周漪,等.浙西常山地区富硒土壤特征及成因分析[J].物探与化探,2019,43(3): 658-666. LIU D R, XU H, ZHOU Y, et al. Characteristics and genetic analysis of selenium-rich soil in Changshan County, western Zhejiang Province[J].Geophysical and Geochemical Exploration, 2019, 43(3): 658-666.
[9] 贾十军.安徽省富硒土壤评价标准及富硒土壤成因浅析[J].华东地质,2013,34(2):133-137. JIA S J.Evaluation standards and genesis of selenium-rich soil in Anhui Province[J]. East China Geology, 2013,34(2):133-137.
[10]王美华.浙西典型石煤矿山周边耕地富硒土壤地球化学特征及影响因素[J].现代地质,2022,36(3): 941-952. WANG M H. Geochemical characteristics and influencing factors of selenium-enriched soils in cultivated land around typical stone coal mines in western Zhejiang [J].Geoscience,2022,36(3):941-952.
[11]王运,邹勇军,王鹤,等.江西信丰油山地区土壤硒及重金属元素地球化学特征[J].华东地质,2019,40(2):152-160. WANG Y, ZOU Y J, WANG H, et al. Geochemical characteristics of Se and heavy metal elements in the soil of Youshan, Xinfeng County, Jiangxi Province[J].East China Geology,2019,40(2):152-160.
[12]刘健,汪一凡,林钟扬,等.浙江建德市耕地表层土壤硒分布、来源及生态效应[J].现代地质,2022,36(3): 953-962. LIU J, WANG Y F, LIN Z Y, et al. Distribution, sources and ecological effects of selenium in topsoil of cultivated land in Jiande City, Zhejiang Province [J]. Geoscience,2022,36(3): 953-962.
[13]郑雄伟,倪倩,郑国权,等.洪湖市峰口—万全地区土壤重金属和硒元素形态组成特征[J].华东地质,2018,39(4):311-318. ZHENG X W, NI Q,ZHENG G Q, et al. Occurrence features of heavy metals and selenium in soil of the Fengkou-Wanquan area, Honghu City[J].East China Geology,2018,39(4):311-318.
[14]吴跃东,向钒,马玲,等.安徽石台大山地区硒的地球化学研究[J].矿物岩石,2007,27(4):53-59. WU Y D, XIANG F, MA L, et al. The geochemistry study of selenium in the stone mountain area of Anhui Province[J]. Mineralogy and Petrology, 2007,27(4):53-59.
[15]XING K, ZHOU S B, WU X G, et al. Concentrations and characteristics of selenium in soil samples from Dashan region, a selenium-enriched area in China[J]. Soil Science and Plant Nutrition,2015,61(6): 889-897.
[16]邢琛,周守标,赵冰,等.大山村地区土壤硒等元素含量及硒与其它元素相关性分析[J].安徽师范大学学报(自然科学版),2020,43(3):249-257. XING C, ZHOU S B, ZHAO B, et al. Contents of selenium(Se) and other elements in soil of dashan area and correlation between selenium(Se) and other elements[J]. Journal of Anhui Normal University (Natural Science), 2020,43(3):249-257.
[17]中华人民共和国国土资源部.DZ/T0295—2016土地质量地球化学评价规范[S].北京:地质出版社,2016:1-59. Ministry of Land and Resources of the People’s Republic of China. DZ/T0295—2016 Specification of land quality geochemical assessment [S]. Beijing: Geological Publishing House,2016: 1-59.
[18]侯青叶,杨忠芳,余涛,等. 中国土壤地球化学参数[M].北京: 地质出版社, 2020. HOU Q Y,YANG Z F,YU T, et al. Soil geochemical parameters in China [M]. Beijing: Geological Publishing House, 2020.
[19]迟清华,鄢明才. 应用地球化学元素丰度数据手册[M].北京: 地质出版社, 2007. CHI Q H, YAN M C. Handbook of elemental abundance for applied geochemistry[M]. Beijing: Geological Publishing House, 2007.
[20]胡艳华,王加恩,蔡子华,等.浙北嘉善地区土壤硒的含量、分布及其影响因素初探[J].地质科技情报,2010,9(6): 84-88. HU Y H,WANG J E,CAI Z H,et al. Content,distribution and influencing factors of selenium in soil of Jiashan area,northern Zhejiang Province[J]. Geological Science and Technology Information,2010,9(6): 84-88.
[21]中华人民共和国生态环境部,国家市场监督管理总局.GB 5084—2021农田灌溉水质标准[S].北京:中国标准出版社,2021:1-8. Ministry of Ecology and Environment of the People’s Republic of China,State Administration for Market Regulation. GB5084—2021 standard for irrigation water quality [S].Beijing: Standards Press of China,2021:1-8.
[22]中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会.GB/T22499—2008富硒稻谷标准[S].北京:中国标准出版社,2008:1-2. General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China,Standardization Administration of the People’s Republic of China. GB/T22499—2008 Rich selenium paddy [S].Beijing: Standards Press of China,2008:1-2.
[23]中华人民共和国农业部.NY-T 600—2002富硒茶[S].北京:中国标准出版社,2002:1-3. The Ministry of Agriculture of the People’s Republic of China. NY-T600—2002 Rich-selenium tea [S].Beijing: Standards Press of China,2002:1-3.
[24]徐聪,刘媛媛,孟凡乔,等.农产品硒含量及与土壤硒的关系[J].中国农学通报,2018,34(7): 96-103. XU C, LIU Y Y, MENG F Q, et al. Selenium content in agricultural products and its relationship with soil selenium[J]. Mineralogy and Petrology,2018,34(7):96-103.
[25]牛雪,何锦,庞雅婕,等.三江平原西部土壤硒分布特征及其影响因素系[J].物探与化探,2021,45(1):223-229. NIU X,HE J,PANG Y J,et al. Distribution feature of soil selenium in west Sanjiang Plain and its influencing factors[J].Geophysical and Geochemical Exploration,2021,45(1):223-229.
[26]World Health Organization. Trace elements in human-nutrition and health [M].Geneva: World Health Organization, 1996.
[27]XU Y F, LI Y H, LI H, et al.Effects of topography and soil properties on soil selenium distribution and bioavailability(phosphate extraction): Acase study in Yongjia County, China[J]. Science of the Total Environment, 2018, 633: 240-248.
[28]LONG Z D, YUAN L X, HOU Y Z, et al. Spatial variations in soil selenium and residential dietary selenium intake in a selenium-rich county, Shitai, Anhui, China[J]. Journal of Trace Elements in Medicine and Biology, 2018, 50: 111-116.
[29]COPPIN F,CHABROULLET C, MARTIN G A selenite interactions with some particulate organic and mineral fractions isolated from a natural grassland soil[J].European Journal of Soil Science,2009,60: 369-376.
[30]TULLO P D,PANNIER F,THIRY Y, et al. Field study of time-dependent selenium partitioning in soils using isotopically enriched stable selenite tracer[J].Science of the Total Environment,2016,562: 280-288.

相似文献/References:

[1]张卫凯,陈少青.广东省揭西县金坑铜锡铅锌矿床地质、地球化学特征及成因[J].华东地质,2015,36(02):137.
[2]柏道远,钟响,贾朋远,等.湘西南苗儿山地区早燕山期花岗岩地球化学特征及形成环境[J].华东地质,2015,36(04):235.
[3]潘仙敏,杨 强,罗 通.安徽西部霍邱周油坊铁矿床地球化学特征及成因[J].华东地质,2016,37(01):52.[doi:10.16788/j.hddz.32-1865/P.2016.01.007]
 PAN Xian-min,YANG Qiang,LUO Tong.Geochemical characteristics and genesis of the Zhouyoufang iron deposit in Huoqiu County, western Anhui Province[J].East China Geology,2016,37(02):52.[doi:10.16788/j.hddz.32-1865/P.2016.01.007]
[4]周雪桂,王水龙,袁承先,等.赣南宁都地区变质岩离子吸附型稀土矿床地球化学特征及找矿意义[J].华东地质,2018,39(03):194.[doi:10.16788/j.hddz.32-1865/P.2018.03.005]
 ZHOU Xue-gui,WANG Shui-long,YUAN Cheng-xian,et al.Geochemistry characteristics of ion-absorbed rare earth deposits in low-grade metamorphic rock in the Ningdu area, southern Jiangxi Province and its prospecting significance[J].East China Geology,2018,39(02):194.[doi:10.16788/j.hddz.32-1865/P.2018.03.005]
[5]郑雄伟,倪 倩,郑国权,等.洪湖市峰口—万全地区土壤重金属和硒元素的形态组成特征[J].华东地质,2018,39(04):311.[doi:10.16788/j.hddz.32-1865/P.2018.04.009]
 ZHENG Xiong-wei,NI Qian,ZHENG Guo-quan,et al.Occurrence features of heavy metals and selenium in soil of the Fengkou-Wanquan area, Honghu[J].East China Geology,2018,39(02):311.[doi:10.16788/j.hddz.32-1865/P.2018.04.009]
[6]写熹,白茹玉,赵华荣.安徽乔木湾地区水系沉积物地球化学特征及找矿远景[J].华东地质,2022,43(02):205.[doi:10.16788/j.hddz.32-1865/P.2022.02.008]
 XIE Xi,BAI Ruyu,ZHAO Huarong.Geochemical characteristics of stream sediments and ore-prospecting in Qiaomuwan area,Anhui Province[J].East China Geology,2022,43(02):205.[doi:10.16788/j.hddz.32-1865/P.2022.02.008]
[7]唐志敏,白晓,湛龙,等.福建省长汀县重点水土流失区土壤元素地球化学特征及其指示意义[J].华东地质,2022,43(03):324.[doi:10.16788/j.hddz.32-1865/P.2022.03.008]
 TANG Zhimin,BAI Xiao,ZHAN Long,et al.Geochemical characteristics and its indicative significance of soil elements in key soil erosive areas of Changting County, Fujian Province[J].East China Geology,2022,43(02):324.[doi:10.16788/j.hddz.32-1865/P.2022.03.008]

备注/Memo

备注/Memo:
收稿日期:2022-4-26;改回日期:2022-9-1。
基金项目:安徽省自然资源科技项目"安徽省高镉富硒土壤资源开发利用研究(编号:2020-K-7)"、安徽省重点研究与开发计划项目"池州市天然富硒土壤开发利用关键技术研究与示范(编号:202004a06020048)"项目资助。
作者简介:李明辉,1987年生,男,高级工程师,硕士,主要从事农业地质和生态地球化学调查评价工作。Email:lmh050121@163.com。
通讯作者:张笑蓉,1989年生,女,工程师,硕士,主要从事生态地球化学调查评价工作。Email:303769045@qq.com。
更新日期/Last Update: 1900-01-01