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    40年来乐清湾潮间带沉积物重金属污染变化及生态风险评价

    Changes in heavy metal pollution and ecological risk assessment of intertidal sediments in Yueqing Bay over the past 40 years

    • 摘要: 潮间带沉积物中的重金属元素易通过食物链的传递和累积对生态系统产生威胁,研究其含量变化对于生态环境安全具有重要意义。为探讨40年来乐清湾潮间带表层沉积物中典型重金属污染水平及潜在生态环境影响,文章收集了1982年、2007年和2021年的沉积物样品分析数据,采用单因子指数法和Hakanson生态风险指数法,分析了Hg、Cd、As、Pb、Cu、Cr和Zn等7种重金属元素含量。结果表明:①1982—2021年乐清湾潮间带表层沉积物的重金属含量总体呈现“先升高、后降低”的变化趋势。②从单因子污染物污染指数Cf来看,Cu始终为重度污染,Cr、Pb和Zn始终处于中度污染,Cd在2007年从中度污染转变为重度污染,Hg和As则经历了“低度-中度-低度”污染的转变。③地质累积指数显示,在研究期内始终没有As、Hg的污染,1982—2007年多数站位的沉积物可能受到了Cu、Cd、Cr、Pb和Zn的污染,2007年之后Cr、Pb无污染。④单个污染物的潜在生态风险指数显示,1982—2021年As、Cr、Cu、Pb和Zn都处于低度生态风险;Cd在1982年处于中度生态风险,在2007年、2021年处于较重度生态风险;Hg在1982年和2021年处于低度生态风险,在2007年处于中度生态风险。⑤从潜在生态风险指数(RI)来看,2007年和2021年各有90%以上的站位为中度潜在生态风险,2021年部分站位从中度-重度潜在生态风险转变为轻度-中度潜在生态风险。总体来看,乐清湾潮间带近20年来生态环境明显改善,但仍需注意Cu和Cd这两种重金属的污染状况。

       

      Abstract: Heavy metal elements in the sediments of the intertidal zone are prone to posing threats to the ecosystem through the transmission and accumulation in the food chain. Studying the variations holds significant importance for the security of the ecological environment. To explore the pollution levels and potential ecological and environmental impacts of typical heavy metals in the surface sediments of the intertidal zone of Yueqing Bay over the past 40 years, this study collected and analyzed the data of sediment samples from 1982, 2007 and 2021. By adpoting single factor index and Hakanson ecological risk index, we analyzed the content of seven heavy metals, i.e. Hg, Cd, As, Pb, Cu, Cr and Zn. The results indicated that ①the contents of heavy metals in the surface sediments of Yueqing Bay generally exhibited a changing trend of “first increasing and then decreasing” during the period from 1982 to 2021. ②Judging from the single factor pollutant pollution index Cf, Cu has always been severely polluted, Cr, Pb and Zn have been moderately polluted. Cd changed from moderately polluted to severely polluted in 2007, while Hg and As underwent a transformation from low to moderate and then back to low pollution. ③The geological accumulation index revealed that there has been no pollution of As and Hg throughout. The sediments at most locations might have been contaminated by Cu, Cd, Cr, Pb, and Zn from 1982 to 2007. After 2007, there was no pollution of Cr and Pb. ④The potential ecological risk index of individual pollutants demonstrated that As, Cr, Cu, Pb and Zn were all at low ecological risk from 1982 to 2021. The Cd element was at moderate ecological risk in 1982 and at relatively severe ecological risk in 2007 and 2021. The Hg element was at low ecological risk in 1982 and 2021 and at moderate ecological risk in 2007. ⑤In terms of the potential ecological risk index RI, over 90% of the stations were at moderate potential ecological risk in 2007 and 2021, and some stations shifted from moderate-severe potential ecological risk to mild-moderate potential ecological risk in 2021. Generally speaking, the ecological environment of the intertidal zone of Yueqing Bay has improved significantly in the past 20 years. However, it is still necessary to pay attention to the pollution conditions of Cu and Cd.

       

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